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2012-08-09 14:03:50
<section class="_135editor" data-role="paragraph" style="max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><section data-role="outer" class="article135" label="edit by 135editor" style="font-size: medium;"><section class="_135editor" data-role="paragraph" style="max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> 答 亚氯酸钠是一种较温和的氧化剂,可用于棉、合纤及其混纺织物的漂白,但不适用于蛋白质纤维的漂白。亚氯酸钠有固体和液体两种,固体含量为80%左右,液体含量有10%和25%,工厂使用多数为液体。亚氯酸钠在碱性条件下较为稳定(一般pH一10时,可长期贮存不分解)。在酸性条件下易分解,其分解速度随pH值降低及温度升高而加快。当pH值为2.4~3 时,ClO2生成量达到最高值;而当pH值低于4.8时,ClO3-的生成量随pH值降低而增加。因此,亚漂的漂白效果与漂液浓度、温度、pH值及漂白时间有关。漂液的pH值能影响亚氯酸钠的利用率,pH值增高亚氯酸钠的利用率也高,但对织物白度及纤维损伤有较大影响。当pH值为2.6时,纤维损伤最为严重,这是由于纤维的酸水解引起的;当pH值为7或大于7时,纤维损伤也较严重,这是由于纤维素被氧化而造成的。在以上pH值范围内漂白,织物白度也较差,所以亚漂时一定要掌握好漂液pH值,实践证明当pH值为4.6~5.5时,可获得较好的白度且纤维损伤亦最小,漂白速度也较适中。实际生产中,为提高漂白速度,通常将漂液pH值调节在4~4.5。由于亚氯酸钠是碱性的,而在漂白时要将碱性亚氯酸钠调整至酸性,因此必须加入酸化剂也称活化剂。活化剂种类较多。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> ①酸活化剂,如有机酸(蚁酸、乳酸、醋酸等)、无机酸(硫酸、盐酸等)。用酸活化剂时有大量二氧化氯逸出,对劳动保护十分不利且设备腐蚀严重。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> ②酯活化剂,如乳酸乙酯、酒石酸二乙酯、醋酸乙酯等。用酯活化价格高、汽蒸条件要求高。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> ③铵活化剂,如硫酸铵、醋酸铵、六亚甲基四胺、硫酸联铵等。用铵活化剂较为理想。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> 现将亚氯酸钠平幅连续轧漂工艺介绍如下。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> 工艺流程:浸轧漂液→汽蒸→水洗→脱氯→水洗。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> 工艺条件:轧液率80%~90%,轧漂温度:室温,汽蒸100~102℃、60~90min,脱氯用硫代硫酸钠1.5~2.0g/L,纯碱1.5~2g/L。工艺处方:亚氯酸钠(100%)15~25g/L,渗透剂2~4g/L,硫酸联铵0.5g/L,漂前漂液pH值4~4.5(先用硫酸使亚氯酸钠pH值降至中性,再加硫酸联铵使pH值降至4~4.5)。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="font-size: 15px;"> </span></p></section><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><br></p></section><section class="_135editor" data-role="paragraph" style="max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="margin-bottom: 0px; max-inline-size: 100%; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br></p></section><section data-role="paragraph" class="_135editor"><p><br></p></section></section></section></section>