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2012-09-12 15:27:17
<div><br></div><div><section class="_135editor" data-role="paragraph" style="font-size: medium; max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> 答 低聚物又称齐聚物,是存在于涤纶内部的一种与涤纶相同化学结构的低分子物。它是在涤纶纺制过程中的副产物。一般涤纶中含有1%~3%的低聚物,它们主要由环状三聚体及线型低聚物所组成。线型低聚物可部分溶于水;环状三聚体不溶于水,只有在纤维本身及染料聚集中可以测得,当温度超过120℃时,可从纤维中析出并与凝聚的染料结合,染色后能造成染斑、色点等疵病。有人曾将此染疵做过分析,其主要成分为:低聚物50%,染料分散剂30%,纤维屑杂质20%。由此可见,色斑色点中低聚物占50%。去除低聚物造成的色斑、色点及克服方法如下。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> ①控制染色温度在120℃)以下,采用适当加用载体染色方法,可减少低聚物的产生并可同样获得染色深度。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> ②染色后,将染液自高温急速排出机外,排液时间最多5min,因低聚物在温度100q~120℃时均匀分布于染液中,温度在100℃以下时易积聚沉淀在染色物上。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> ③在染色时加入分散保护胶质助剂,如Uniperol PE,既可产生匀集效果,还可阻止低聚物在织物上沉淀。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> ④染色后用还原剂清洗:32.5%(38°Bé)NaOH 3~5mL/L,保险粉3~4g/L,Uniperol PE 0.5~1g/L,70℃处理30min,然后冷洗、热洗、冷洗,用醋酸中和。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> ⑤染前处理。坯布在染色前采用100% NaOH 3%(对布重),表面活性洗涤剂1%(对布重),于130℃下处理60min,浴比1:(10~15)。采用染前处理法对涤纶有一定侵蚀作用,但对去除低聚物极为有利。对涤纶长丝织物可减少“极光”,对中短纤维可改善起毛起球现象。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p></section><section class="_135editor" data-role="paragraph" id="autoparagraph" style="font-size: medium; max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; font-family: 微软雅黑, "Microsoft YaHei", sans-serif; font-size: 17px; caret-color: rgb(255, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"></p></section></div>