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2012-04-27 10:52:51
<section data-role="paragraph" class="_135editor" style="max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><section data-role="paragraph" class="_135editor" style="max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"> 答 根据前苏联学者的研究,在棉织物碱煮练浴中加入蒽醌或蒽醌磺酸衍生物,在煮练后以双氧水漂白,对棉及涤棉混纺织物均有缩短煮练时间、增加除杂率和提高毛效、白度的效果,对棉织物尚有一定的保护作用。国内曾有人做了试验,用27.77texX27.77tex(21英支×21英支)纯棉细乎布,用NaOH 20g/L、水玻璃0.5%(owf)、磷酸三钠0.5%(owf)、渗透剂JFC 1%(owf)、蒽醌(简称AQ)2g/L及2~蒽醌磺酸钠(简称AQS)29/L,于130℃、60min,在RJ--1180型高温高压染色机中煮练后,对去杂、毛效、白度和强力等指标测试,并在相同条件下加入NaHS03作对比。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"> 其结果为:去杂效果以AQS为最好,白度以AQ、AQS为最好;毛效以AQ、AQS为最大;强力损伤以AQ、AQS为最小。实验证明,AQ及AQS在棉布煮练中对棉纤维具有较佳催化效果,其效果比NaHS03要好。究其原理可以认为:纤维素是以1,4一苷键结合的β一葡萄糖大分子链,其端基上残存有游离醛基,而纤维素的共生物中,如半纤维素是聚合度较低的葡萄糖大分子,果胶质为聚半乳糖醛酸、聚戊糖和聚己糖等的大分子量的复合化合物。由于果胶质中含有较多的糖醛酸剩基,且相对分子质量较低,因而游离醛基含量的摩尔百分数较纤维素大分子链为高,具有一定的还原性,从而可使蒽醌及蒽醌磺酸钠还原为氢醌形式,而本身氧化成羧酸。蒽醌还原为氢醌形式这一点可从煮练浴中蒽醌(黄色)及蒽醌磺酸钠(黄色)分别呈现出红棕色反映出来。而果胶质本身在高温和碱的作用下会逐渐水解,且因糖醛酸羧基的作用而溶于煮练液中。由于蒽醌的作用,果胶质中部分游离醛基成为羧基,不仅增大了其水溶性,且能加速多聚糖的水解,从而对果胶质的去除起到催化加速作用。因此可以认为,亚硫酸氢钠可与木质素作用生成木质素磺酸钠。但AQ、AQS不仅对木质素起作用,而且对棉籽壳的去除效果要优于NaHS03。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"> 注:owf表示按织物重量计算。</span></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; 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