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2012-12-11 13:50:29
<br><div><section class="_135editor" data-role="paragraph" style="font-size: medium; max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); font-size: 14px; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> 答 有效降低甲醛释放量的办法主要有两种途径。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); font-size: 14px; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> ①将不断游离的甲醛进行羟甲基醚化。当用低级醇醚化羟甲基时,可提高C-N键的稳定性,这时未反应的游离甲醛也可与醇反应生成缩醛或半缩醛,从而降低甲醛的游离和释放量。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); font-size: 14px; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> 一般常用甲醇、乙醇、二甘醇等,经醚化的2D树脂、三聚氰胺树脂产品中游离甲醛可降至0.3%以下。其中甲醇醚化的2D树脂可使甲醛释放量降至300mg/kg,而二甘醇变性的更低,达lOOmg/kg以内。经醚化改性的羟甲基树脂一般反应性均较未改性前低,可应用氯化镁与柠檬酸混合催化剂等高效催化剂,这一类树脂还有高度醚化和部分醚化两种,制造时以二步法较一步法工艺降低甲醛效果明显。反应过程中要严格控制pH值、反应温度及反应时间。值得推荐的是选用二甘醇。当二甘醇与2D树脂以2:1(摩尔比)混合时,甲醛释放量有明显降低。也有人曾将聚醚改性硅油CGF与2D树脂并用,3~4g/L CGF还可减少2D树脂用量30%~50%,游离甲醛可降低70%~80%。</span></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); font-size: 14px; text-align: center; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><img src="http://dayaotex-img.gz.bcebos.com/article/fffspic/houzhengli19.jpg" _src="http://dayaotex-img.gz.bcebos.com/article/fffspic/houzhengli19.jpg" data-ratio="0.3752665245202559" data-w="469" style="max-inline-size: 100%; margin: 0px; padding: 0px; max-width: 100%; width: 444px; overflow-wrap: break-word !important; outline: none 0px !important; height: auto !important;"></p></section><section style="max-inline-size: 100%; margin: 0px; padding: 0px; -webkit-tap-highlight-color: rgba(0, 0, 0, 0); font-size: 14px; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; line-height: 1.75em; overflow-wrap: break-word !important; outline: none 0px !important;"><span style="max-inline-size: 100%; margin: 0px; padding: 0px; cursor: text; font-size: 15px; overflow-wrap: break-word !important; outline: none 0px !important;"> 上述两种方法不能根除甲醛的危害,只能减少甲醛的释放量。而要彻底根除甲醛问题,则生产中必须不使用甲醛(包括不用由甲醛反应生成的原料生产的产品)。</span></p></section><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; overflow-wrap: break-word !important; outline: none 0px !important;"></p></section><section class="_135editor" data-role="paragraph" id="autoparagraph" style="font-size: medium; max-inline-size: 100%; margin: 0px; padding: 0px; border: 0px none; z-index: 0; overflow-wrap: break-word !important; outline: none 0px !important;"><p style="max-inline-size: 100%; margin-bottom: 0px; clear: both; min-height: 1em; cursor: text; overflow-wrap: break-word !important; outline: none 0px !important;"><br style="max-inline-size: 100%; margin: 0px; padding: 0px; font-family: 微软雅黑, "Microsoft YaHei", sans-serif; font-size: 17px; caret-color: rgb(255, 0, 0); overflow-wrap: break-word !important; outline: none 0px !important;"></p></section></div>